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tert-butyl 4-(3-methoxy-3-oxo-propyl)piperidine-1-carboxylate
tert-butyl 4-(3-methoxy-3-oxo-propyl)piperidine-1-carboxylate ID: AN-31203
CAS:162504-75-8
Supplier:AN PharmaTech Co Ltd

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SMILES:O(C(=O)N1CCC(CC1)CCC(=O)OC)C(C)(C)C	1502093
FORMULA: C14H25NO4
MASS: 271.3526
EXACT MASS: 271.1783583
INTERATOMIC DISTANCES

              O   1      O   2      O   3      O   4      N   5      C   6
              ------------------------------------------------------------------
   O   1    0.0000 
   O   2    1.7320     0.0000 
   O   3    7.0000     6.5574     0.0000 
   O   4    6.5574     6.5574     1.7321     0.0000 
   N   5    1.7320     1.7320     5.2915     5.0000     0.0000 
   C   6    3.6055     3.6055     3.4641     3.0000     2.0000     0.0000 
   C   7    3.4641     3.0000     3.6056     3.6055     1.7320     1.0000 
   C   8    3.0000     3.4641     4.3589     3.6055     1.7320     1.0000 
   C   9    2.0000     2.6457     5.1962     4.5826     1.0000     1.7320 
   C  10    2.6457     2.0000     4.5826     4.5826     1.0000     1.7320 
   C  11    4.5826     4.5826     2.6458     2.0000     3.0000     1.0000 
   C  12    5.2915     5.0000     1.7321     1.7320     3.6055     1.7320 
   C  13    1.0000     1.0000     6.2450     6.0000     1.0000     3.0000 
   C  14    1.0000     2.0000     7.9373     7.5498     2.6457     4.5826 
   C  15    6.2450     6.0000     1.0001     1.0000     4.5826     2.6457 
   C  16    2.0000     2.6457     8.8882     8.5440     3.6055     5.5678 
   C  17    1.4142     2.9093     8.3184     7.7286     3.1196     4.8715 
   C  18    1.4142     1.2393     7.6684     7.5012     2.5036     4.5020 
   C  19    7.9373     7.5498     1.0000     2.0000     6.2450     4.3589 
   H  20    4.0601     3.8242     2.9435     2.7431     2.3716     0.6201 
   H  21    3.7220     2.9561     3.6167     3.8982     2.0295     1.5968 
   H  22    4.0761     3.5889     2.9898     3.1102     2.3451     1.0813 
   H  23    3.5889     4.0760     4.0507     3.1102     2.3451     1.0812 
   H  24    2.9561     3.7220     4.8282     3.8982     2.0295     1.5968 
   H  25    2.1944     3.1512     5.4395     4.6339     1.5968     2.0295 
   H  26    1.4332     2.4059     5.8077     5.1957     1.0812     2.3451 
   H  27    2.4059     1.4332     5.1245     5.1957     1.0813     2.3451 
   H  28    3.1512     2.1944     4.3997     4.6339     1.5968     2.0295 
   H  29    5.1245     5.1957     2.4059     1.4332     3.5889     1.5967 
   H  30    4.3997     4.6339     3.1513     2.1944     2.9561     1.0812 
   H  31    4.8263     4.4225     2.1829     2.3451     3.1102     1.4156 
   H  32    5.6193     5.1441     1.4155     2.0295     3.8982     2.1829 
   H  33    2.0939     3.0874     9.0888     8.6289     3.8024     5.6972 
   H  34    2.6200     3.1407     9.4829     9.1610     4.2100     6.1810 
   H  35    2.0939     2.2883     8.7271     8.5036     3.5086     5.5055 
   H  36    1.0698     2.7583     7.7641     7.1286     2.6488     4.3054 
   H  37    1.9038     3.4980     8.6048     7.9013     3.5256     5.1410 
   H  38    1.9038     1.7777     8.2758     8.1211     3.1229     5.1218 
   H  39    1.9038     1.0063     7.5635     7.5378     2.6112     4.5627 
   H  40    1.0698     0.8248     7.0632     6.8813     1.8848     3.8823 
   H  41    1.9038     3.1762     8.8815     8.3316     3.6354     5.4494 
   H  42    8.1613     7.6458     1.1766     2.5559     6.4446     4.6403 
   H  43    8.5255     8.1661     1.6200     2.3716     6.8428     4.9340 
   H  44    7.7565     7.5040     1.1766     1.4956     6.1022     4.1517 

              C   7      C   8      C   9      C  10      C  11      C  12
              ------------------------------------------------------------------
   C   7    0.0000 
   C   8    1.7320     0.0000 
   C   9    2.0000     1.0000     0.0000 
   C  10    1.0000     2.0000     1.7320     0.0000 
   C  11    1.7320     1.7320     2.6457     2.6457     0.0000 
   C  12    2.0000     2.6457     3.4641     3.0000     1.0000     0.0000 
   C  13    2.6457     2.6457     1.7320     1.7320     4.0000     4.5826 
   C  14    4.3589     4.0000     3.0000     3.4641     5.5678     6.2450 
   C  15    3.0000     3.4641     4.3589     4.0000     1.7320     1.0000 
   C  16    5.2915     5.0000     4.0000     4.3589     6.5574     7.2111 
   C  17    4.8439     4.1231     3.1623     4.0576     5.8079     6.5927 
   C  18    4.0664     4.1231     3.1623     3.0880     5.5016     6.0445 
   C  19    4.5826     5.1962     6.0828     5.5678     3.4641     2.6458 
   H  20    0.8743     1.6200     2.2901     1.8397     0.8743     1.2346 
   H  21    0.6200     2.3451     2.5068     1.0812     2.1829     2.1944 
   H  22    0.6200     2.0295     2.5068     1.5967     1.4156     1.4332 
   H  23    2.0294     0.6200     1.5967     2.5067     1.4155     2.4059 
   H  24    2.3451     0.6200     1.0812     2.5068     2.1829     3.1512 
   H  25    2.5068     1.0812     0.6200     2.3451     2.8113     3.7220 
   H  26    2.5067     1.5967     0.6200     2.0294     3.2657     4.0760 
   H  27    1.5967     2.5068     2.0295     0.6200     3.2657     3.5889 
   H  28    1.0812     2.5068     2.3451     0.6200     2.8113     2.9561 
   H  29    2.3451     2.1829     3.1512     3.2657     0.6200     1.0812 
   H  30    2.0295     1.4155     2.4059     2.8113     0.6200     1.5968 
   H  31    1.4332     2.4059     3.1022     2.4267     1.0813     0.6200 
   H  32    2.1944     3.1512     3.8917     3.1671     1.5968     0.6200 
   H  33    5.5256     5.0383     4.0478     4.6402     6.6677     7.3846 
   H  34    5.8808     5.6200     4.6200     4.9340     7.1725     7.8144 
   H  35    5.1222     5.0383     4.0478     4.1517     6.5047     7.0878 
   H  36    4.3461     3.5248     2.5815     3.6233     5.2246     6.0339 
   H  37    5.2188     4.3156     3.4095     4.4984     6.0357     6.8728 
   H  38    4.6776     4.7270     3.7556     3.6933     6.1215     6.6603 
   H  39    4.0016     4.3156     3.4095     3.0021     5.5514     6.0010 
   H  40    3.4584     3.5248     2.5815     2.4900     4.8818     5.4296 
   H  41    5.3673     4.7270     3.7556     4.5352     6.3982     7.1616 
   H  42    4.7390     5.5323     6.3723     5.6972     3.8121     2.9083 
   H  43    5.1927     5.7415     6.6486     6.1810     4.0131     3.2380 
   H  44    4.5067     4.9156     5.8449     5.5055     3.1995     2.5121 

              C  13      C  14      C  15      C  16      C  17      C  18
              ------------------------------------------------------------------
   C  13    0.0000 
   C  14    1.7320     0.0000 
   C  15    5.5678     7.2111     0.0000 
   C  16    2.6457     1.0000     8.1853     0.0000 
   C  17    2.3942     1.0000     7.5142     1.4142     0.0000 
   C  18    1.5060     1.0000     7.0382     1.4142     2.0000     0.0000 
   C  19    7.2111     8.8882     1.7321     9.8489     9.2302     8.6489 
   H  20    3.3533     5.0104     2.2146     5.9770     5.3768     4.8269 
   H  21    2.8113     4.5429     3.1671     5.4242     5.1306     4.1174 
   H  22    3.2657     4.9779     2.4267     5.9114     5.4468     4.6788 
   H  23    3.2657     4.5875     3.1021     5.5866     4.6499     4.7402 
   H  24    2.8113     3.9399     3.8917     4.9303     3.9117     4.2124 
   H  25    2.1829     3.1671     4.5429     4.1528     3.1320     3.5003 
   H  26    1.4155     2.4267     4.9779     3.4240     2.5426     2.7042 
   H  27    1.4156     3.1022     4.5875     3.9317     3.8094     2.5952 
   H  28    2.1829     3.8917     3.9399     4.7287     4.5641     3.3853 
   H  29    4.5875     6.1177     1.4155     7.1127     6.3035     6.0924 
   H  30    3.9399     5.3983     2.1829     6.3974     5.5365     5.4435 
   H  31    4.0630     5.7557     1.5967     6.7054     6.1657     5.4990 
   H  32    4.8385     6.5415     1.0812     7.4838     6.9625     6.2535 
   H  33    2.9083     1.1766     8.3386     0.6200     1.0698     1.9038 
   H  34    3.2380     1.6200     8.7923     0.6200     1.9038     1.9038 
   H  35    2.5121     1.1766     8.0769     0.6200     1.9038     1.0698 
   H  36    2.0631     1.1766     6.9403     1.9038     0.6200     2.0939 
   H  37    2.9035     1.6200     7.7612     1.9038     0.6200     2.6200 
   H  38    2.1242     1.1766     7.6551     1.0698     2.0939     0.6200 
   H  39    1.6788     1.6200     7.0009     1.9038     2.6200     0.6200 
   H  40    0.8901     1.1766     6.4219     1.9038     2.0939     0.6200 
   H  41    2.8242     1.1766     8.0950     1.0698     0.6200     2.0939 
   H  42    7.3846     9.0888     2.1115    10.0303     9.4891     8.7846 
   H  43    7.8144     9.4829     2.2901    10.4482     9.8041     9.2590 
   H  44    7.0878     8.7271     1.5201     9.7038     9.0066     8.5561 

              C  19      H  20      H  21      H  22      H  23      H  24
              ------------------------------------------------------------------
   C  19    0.0000 
   H  20    3.8787     0.0000 
   H  21    4.6148     1.3134     0.0000 
   H  22    3.9716     0.5869     0.7971     0.0000 
   H  23    4.8211     1.6309     2.6462     2.1561     0.0000 
   H  24    5.6149     2.2129     2.9532     2.6463     0.7971     0.0000 
   H  25    6.2748     2.6367     3.0556     2.9499     1.5278     0.7846 
   H  26    6.7003     2.8867     2.9498     3.0556     2.1652     1.5278 
   H  27    6.1177     2.4530     1.5278     2.1652     3.0556     2.9499 
   H  28    5.3983     1.9444     0.7846     1.5278     2.9498     3.0556 
   H  29    3.1022     1.4767     2.7656     1.9785     1.7320     2.5292 
   H  30    3.8918     1.2869     2.5703     1.8728     0.9349     1.7320 
   H  31    3.1512     0.8135     1.5763     0.8348     2.3121     2.9753 
   H  32    2.4059     1.6021     2.2154     1.5763     2.9752     3.6918 
   H  33   10.0303     6.1521     5.7194     6.1433     5.5975     4.8923 
   H  34   10.4482     6.5813     5.9894     6.5001     6.2062     5.5460 
   H  35    9.7038     5.8625     5.1867     5.7375     5.6443     5.0447 
   H  36    8.6626     4.8302     4.6777     4.9366     4.0402     3.2954 
   H  37    9.4891     5.6811     5.5545     5.8054     4.7940     4.0211 
   H  38    9.2590     5.4449     4.7078     5.2876     5.3419     4.7911 
   H  39    8.5561     4.8149     3.9588     4.5940     4.9352     4.4862 
   H  40    8.0404     4.2093     3.5370     4.0735     4.1438     3.6472 
   H  41    9.8041     5.9380     5.6155     5.9779     5.2619     4.5291 
   H  42    0.6200     4.1123     4.6901     4.1194     5.2069     5.9908 
   H  43    0.6200     4.4726     5.2339     4.5843     5.3371     6.1339 
   H  44    0.6200     3.7345     4.6221     3.9175     4.4880     5.2851 

              H  25      H  26      H  27      H  28      H  29      H  30
              ------------------------------------------------------------------
   H  25    0.0000 
   H  26    0.7971     0.0000 
   H  27    2.6463     2.1561     0.0000 
   H  28    2.9532     2.6462     0.7971     0.0000 
   H  29    3.2325     3.7661     3.8856     3.4207     0.0000 
   H  30    2.4432     3.0114     3.4208     3.0945     0.7971     0.0000 
   H  31    3.4440     3.6944     3.0000     2.3438     1.4515     1.6889 
   H  32    4.2097     4.4882     3.7118     3.0000     1.6888     2.2064 
   H  33    4.1077     3.4417     4.2724     5.0646     7.1963     6.4520 
   H  34    4.7670     4.0430     4.4811     5.2763     7.7303     7.0169 
   H  35    4.2881     3.5172     3.6650     4.4543     7.0827     6.4027 
   H  36    2.5180     1.9625     3.4494     4.1667     5.7075     4.9347 
   H  37    3.2675     2.7976     4.3066     5.0359     6.4938     5.7091 
   H  38    4.0608     3.2703     3.1807     3.9621     6.7115     6.0582 
   H  39    3.8254     3.0332     2.4390     3.1906     6.1588     5.5623 
   H  40    2.9636     2.1679     2.0303     2.8269     5.4735     4.8300 
   H  41    3.7480     3.1380     4.2301     5.0069     6.9037     6.1420 
   H  42    6.6133     6.9831     6.2146     5.4629     3.5240     4.2936 
   H  43    6.8149     7.2678     6.7344     6.0177     3.6063     4.4027 
   H  44    5.9815     6.4649     6.0827     5.4046     2.7563     3.5532 

              H  31      H  32      H  33      H  34      H  35      H  36
              ------------------------------------------------------------------
   H  31    0.0000 
   H  32    0.7971     0.0000 
   H  33    6.9107     7.7004     0.0000 
   H  34    7.3010     8.0750     0.8768     0.0000 
   H  35    6.5526     7.3135     1.2400     0.8768     0.0000 
   H  36    5.6287     6.4256     1.6640     2.4531     2.2910     0.0000 
   H  37    6.4847     7.2805     1.4142     2.2910     2.4531     0.8768 
   H  38    6.1108     6.8604     1.6640     1.4142     0.5374     2.3532 
   H  39    5.4271     6.1503     2.4531     2.2910     1.4142     2.6924 
   H  40    4.8894     5.6496     2.2910     2.4531     1.6640     2.0000 
   H  41    6.7170     7.5123     0.5374     1.4142     1.6640     1.2400 
   H  42    3.3355     2.5475    10.2460    10.6193     9.8489     8.9379 
   H  43    3.7599     3.0231    10.6193    11.0498    10.3115     9.2302 
   H  44    3.0828     2.4199     9.8489    10.3115     9.5966     8.4240 

              H  37      H  38      H  39      H  40      H  41      H  42
              ------------------------------------------------------------------
   H  37    0.0000 
   H  38    2.6924     0.0000 
   H  39    3.2400     0.8768     0.0000 
   H  40    2.6924     1.2400     0.8768     0.0000 
   H  41    0.8768     2.0000     2.6924     2.3532     0.0000 
   H  42    9.7805     9.3859     8.6489     8.1862    10.0482     0.0000 
   H  43   10.0482     9.8702     9.1723     8.6489    10.3833     0.8768 
   H  44    9.2302     9.1723     8.5075     7.9405     9.5939     1.2400 

              H  43      H  44
              ----------------------
   H  43    0.0000 
   H  44    0.8768     0.0000 



ATOMIC CHARGES
   O   1   -0.4445314459
   O   2   -0.2262375538
   O   3   -0.4679237869
   O   4   -0.2508630902
   N   5   -0.2674040174
   C   6   -0.0377017868
   C   7   -0.0341392582
   C   8   -0.0341392582
   C   9    0.0180485668
   C  10    0.0180485668
   C  11   -0.0400367097
   C  12    0.0451798220
   C  13    0.4033613736
   C  14    0.1067898903
   C  15    0.3068238140
   C  16   -0.0253133083
   C  17   -0.0253133083
   C  18   -0.0253133083
   C  19    0.0816559385
   H  20    0.0301871315
   H  21    0.0283038233
   H  22    0.0283038233
   H  23    0.0283038233
   H  24    0.0283038233
   H  25    0.0465541317
   H  26    0.0465541317
   H  27    0.0465541317
   H  28    0.0465541317
   H  29    0.0273071923
   H  30    0.0273071923
   H  31    0.0377544311
   H  32    0.0377544311
   H  33    0.0267782877
   H  34    0.0267782877
   H  35    0.0267782877
   H  36    0.0267782877
   H  37    0.0267782877
   H  38    0.0267782877
   H  39    0.0267782877
   H  40    0.0267782877
   H  41    0.0267782877
   H  42    0.0660873574
   H  43    0.0660873574
   H  44    0.0660873574


BOND ANGLES
  13    1   14   C2   O3   C3    120.001
  15    3   19   C2   O3   C3    119.998
   9    5   10   C3  Nam   C3    119.999
   9    5   13   C3  Nam   C2    120.001
  10    5   13   C3  Nam   C2    120.001
   7    6    8   C3   C3   C3    119.999
   7    6   11   C3   C3   C3    120.001
   7    6   20   C3   C3   HC     59.998
   8    6   11   C3   C3   C3    120.001
   8    6   20   C3   C3   HC    179.974
  11    6   20   C3   C3   HC     60.003
   6    7   10   C3   C3   C3    120.001
   6    7   21   C3   C3   HC    160.002
   6    7   22   C3   C3   HC     80.004
  10    7   21   C3   C3   HC     79.997
  10    7   22   C3   C3   HC    159.996
  21    7   22   HC   C3   HC     79.999
   6    8    9   C3   C3   C3    120.001
   6    8   23   C3   C3   HC     79.995
   6    8   24   C3   C3   HC    160.002
   9    8   23   C3   C3   HC    160.004
   9    8   24   C3   C3   HC     79.997
  23    8   24   HC   C3   HC     80.007
   5    9    8  Nam   C3   C3    120.001
   5    9   25  Nam   C3   HC    160.002
   5    9   26  Nam   C3   HC     79.995
   8    9   25   C3   C3   HC     79.997
   8    9   26   C3   C3   HC    160.004
  25    9   26   HC   C3   HC     80.007
   5   10    7  Nam   C3   C3    120.001
   5   10   27  Nam   C3   HC     80.004
   5   10   28  Nam   C3   HC    160.002
   7   10   27   C3   C3   HC    159.996
   7   10   28   C3   C3   HC     79.997
  27   10   28   HC   C3   HC     79.999
   6   11   12   C3   C3   C3    120.001
   6   11   29   C3   C3   HC    160.004
   6   11   30   C3   C3   HC     79.997
  12   11   29   C3   C3   HC     79.995
  12   11   30   C3   C3   HC    160.002
  29   11   30   HC   C3   HC     80.007
  11   12   15   C3   C3   C2    120.001
  11   12   31   C3   C3   HC     80.004
  11   12   32   C3   C3   HC    160.002
  15   12   31   C2   C3   HC    159.996
  15   12   32   C2   C3   HC     79.997
  31   12   32   HC   C3   HC     79.999
   1   13    2   O3   C2   O2    119.999
   1   13    5   O3   C2  Nam    120.001
   2   13    5   O2   C2  Nam    120.001
   1   14   16   O3   C3   C3    179.974
   1   14   17   O3   C3   C3     90.000
   1   14   18   O3   C3   C3     90.000
  16   14   17   C3   C3   C3     90.000
  16   14   18   C3   C3   C3     90.000
  17   14   18   C3   C3   C3    179.974
   3   15    4   O3   C2   O2    120.001
   3   15   12   O3   C2   C3    119.998
   4   15   12   O2   C2   C3    120.001
  14   16   33   C3   C3   HC     90.000
  14   16   34   C3   C3   HC    179.974
  14   16   35   C3   C3   HC     90.000
  33   16   34   HC   C3   HC     90.000
  33   16   35   HC   C3   HC    179.974
  34   16   35   HC   C3   HC     90.000
  14   17   36   C3   C3   HC     90.000
  14   17   37   C3   C3   HC    179.974
  14   17   41   C3   C3   HC     90.000
  36   17   37   HC   C3   HC     90.000
  36   17   41   HC   C3   HC    179.974
  37   17   41   HC   C3   HC     90.000
  14   18   38   C3   C3   HC     90.000
  14   18   39   C3   C3   HC    179.974
  14   18   40   C3   C3   HC     90.000
  38   18   39   HC   C3   HC     90.000
  38   18   40   HC   C3   HC    179.974
  39   18   40   HC   C3   HC     90.000
   3   19   42   O3   C3   HC     90.000
   3   19   43   O3   C3   HC    179.974
   3   19   44   O3   C3   HC     90.000
  42   19   43   HC   C3   HC     90.000
  42   19   44   HC   C3   HC    179.974
  43   19   44   HC   C3   HC     90.000


TORSION ANGLES
  14    1   13    2      0.026
  14    1   13    5    179.974
  13    1   14   16    180.000
  13    1   14   17    179.974
  13    1   14   18      0.026
  19    3   15    4      0.026
  19    3   15   12    179.974
  15    3   19   42    179.974
  15    3   19   43    180.000
  15    3   19   44      0.026
  10    5    9    8      0.026
  10    5    9   25    179.974
  10    5    9   26    179.974
  13    5    9    8    179.974
  13    5    9   25      0.026
  13    5    9   26      0.026
   9    5   10    7      0.026
   9    5   10   27    179.974
   9    5   10   28    179.974
  13    5   10    7    179.974
  13    5   10   27      0.026
  13    5   10   28      0.026
   9    5   13    1      0.026
   9    5   13    2    179.974
  10    5   13    1    179.974
  10    5   13    2      0.026
   8    6    7   10      0.026
   8    6    7   21    179.974
   8    6    7   22    179.974
  11    6    7   10    179.974
  11    6    7   21      0.026
  11    6    7   22      0.026
  20    6    7   10    179.974
  20    6    7   21      0.026
  20    6    7   22      0.026
   7    6    8    9      0.026
   7    6    8   23    179.974
   7    6    8   24    179.974
  11    6    8    9    179.974
  11    6    8   23      0.026
  11    6    8   24      0.026
  20    6    8    9      0.026
  20    6    8   23    179.974
  20    6    8   24    179.974
   7    6   11   12      0.026
   7    6   11   29    179.974
   7    6   11   30    179.974
   8    6   11   12    179.974
   8    6   11   29      0.026
   8    6   11   30      0.026
  20    6   11   12      0.026
  20    6   11   29    179.974
  20    6   11   30    179.974
   6    7   10    5      0.026
   6    7   10   27    179.974
   6    7   10   28    179.974
  21    7   10    5    179.974
  21    7   10   27      0.026
  21    7   10   28      0.026
  22    7   10    5    179.974
  22    7   10   27      0.026
  22    7   10   28      0.026
   6    8    9    5      0.026
   6    8    9   25    179.974
   6    8    9   26    179.974
  23    8    9    5    179.974
  23    8    9   25      0.026
  23    8    9   26      0.026
  24    8    9    5    179.974
  24    8    9   25      0.026
  24    8    9   26      0.026
   6   11   12   15    179.974
   6   11   12   31      0.026
   6   11   12   32      0.026
  29   11   12   15      0.026
  29   11   12   31    179.974
  29   11   12   32    179.974
  30   11   12   15      0.026
  30   11   12   31    179.974
  30   11   12   32    179.974
  11   12   15    3    179.974
  11   12   15    4      0.026
  31   12   15    3      0.026
  31   12   15    4    179.974
  32   12   15    3      0.026
  32   12   15    4    179.974
   1   14   16   33    180.000
   1   14   16   34    180.000
   1   14   16   35    180.000
  17   14   16   33      0.026
  17   14   16   34    180.000
  17   14   16   35    179.974
  18   14   16   33    179.974
  18   14   16   34    180.000
  18   14   16   35      0.026
   1   14   17   36      0.026
   1   14   17   37    180.000
   1   14   17   41    179.974
  16   14   17   36    179.974
  16   14   17   37    180.000
  16   14   17   41      0.026
  18   14   17   36    180.000
  18   14   17   37    180.000
  18   14   17   41    180.000
   1   14   18   38    179.974
   1   14   18   39    180.000
   1   14   18   40      0.026
  16   14   18   38      0.026
  16   14   18   39    180.000
  16   14   18   40    179.974
  17   14   18   38    180.000
  17   14   18   39    180.000
  17   14   18   40    180.000