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(-)-2,3-Bis[(2R,5R)-2,5-dimethyl-phospholanyl]maleic anhydride(2,5-norbornadiene)rhodium(I) tetrafluoroborate
(-)-2,3-Bis[(2R,5R)-2,5-dimethyl-phospholanyl]maleic anhydride(2,5-norbornadiene)rhodium(I) tetrafluoroborate
ID: BP-12251
Supplier:BroadPharm

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SMILES:C1(=C(C(=O)OC1=O)P1[C@@H](CC[C@H]1C)C)P1[C@@H](CC[C@H]1C)C.[B-](F)(F)(F)F.C1=C[C@@H]2C=C[C@H]1C2.[Rh+]	
FORMULA: C23H32BF4O3P2Rh
MASS: 608.1560
EXACT MASS: 608.0910904
INTERATOMIC DISTANCES

              C   1      C   2      C   3      C   4      P   5      P   6
              ------------------------------------------------------------------
   C   1    0.0000 
   C   2    0.7875     0.0000 
   C   3    0.8079     1.2859     0.0000 
   C   4    1.2858     0.8079     1.2708     0.0000 
   P   5    0.7500     1.4586     1.2724     2.0358     0.0000 
   P   6    1.4428     0.7367     2.0226     1.2678     1.9708     0.0000 
   O   7    1.2729     1.2768     0.7687     0.7789     1.9337     1.9315 
   B   8    5.2594     5.2466     6.0515     6.0335     4.9076     4.8698 
   O   9    2.0302     1.4091     2.0084     0.7658     2.7768     1.5270 
   O  10    1.4149     2.0375     0.7736     2.0166     1.5250     2.7698 
   C  11    1.3771     2.1593     1.4828     2.5812     0.8024     2.7447 
   C  12    2.1476     1.3660     2.5728     1.4790     2.7481     0.8039 
   C  13    1.8608     1.3869     2.5919     2.0578     2.1301     0.8083 
   C  14    1.3940     1.8731     2.0606     2.6022     0.8083     2.1301 
   C  15    3.3616     3.4867     4.1302     4.2942     2.9429     3.2819 
   C  16    2.8208     3.0191     3.5723     3.8250     2.3642     2.9078 
   C  17    3.0493     2.8055     3.8512     3.5396     2.9897     2.3094 
   C  18    3.6018     3.3493     4.4043     4.0700     3.5216     2.8241 
   C  19    2.7643     2.0332     3.3040     2.2926     3.2493     1.3216 
   C  20    2.6044     2.0124     3.2829     2.5233     2.9241     1.2952 
   C  21    2.0419     2.6335     2.5511     3.3123     1.3145     2.9356 
   C  22    2.0319     2.7657     2.2835     3.3009     1.3071     3.2383 
   C  23    3.7752     3.7002     4.5796     4.4796     3.5192     3.3088 
   C  24    3.1976     3.1714     3.9986     3.9647     2.9232     2.8449 
   F  25    4.6794     4.7535     5.4534     5.5558     4.2647     4.4614 
   F  26    5.8002     5.8602     6.5737     6.6589     5.3782     5.5354 
   F  27    5.8958     5.8063     6.6983     6.5710     5.6011     5.3591 
   F  28    4.7973     4.6869     5.6029     5.4501     4.5426     4.2406 
   C  29    4.3662     4.3470     5.1620     5.1357     4.0401     3.9838 
  Rh  30    0.9109     0.9411     1.7167     1.7427     1.0337     1.0841 
   C  31    1.7502     1.9312     2.5298     2.7340     1.4198     1.9105 
   C  32    1.9242     1.7500     2.7277     2.5313     1.9105     1.4198 
   C  33    2.4294     1.6658     2.6356     1.3786     3.1244     1.3797 
   C  34    1.6882     2.4515     1.3973     2.6555     1.3884     3.1309 
   H  35    2.6489     2.5291     3.4568     3.3088     2.4996     2.1594 
   H  36    4.3314     4.1618     5.1393     4.9079     4.1446     3.6796 

              O   7      B   8      O   9      O  10      C  11      C  12
              ------------------------------------------------------------------
   O   7    0.0000 
   B   8    6.4507     0.0000 
   O   9    1.3748     6.3943     0.0000 
   O  10    1.3707     6.4323     2.7209     0.0000 
   C  11    2.2489     5.3636     3.3464     1.2901     0.0000 
   C  12    2.2541     5.2956     1.2968     3.3457     3.5000     0.0000 
   C  13    2.6593     4.0779     2.3187     3.2736     2.9310     1.3001 
   C  14    2.6608     4.1229     3.2795     2.3174     1.3044     2.9320 
   C  15    4.6023     1.9817     4.7812     4.4636     3.3830     3.8930 
   C  16    4.0782     2.5720     4.3633     3.8805     2.7932     3.5866 
   C  17    4.0743     2.6116     3.8141     4.4161     3.6924     2.6840 
   C  18    4.6213     2.2197     4.3068     4.9635     4.2037     3.1265 
   C  19    3.0598     4.8562     2.0976     4.0672     4.0408     0.8268 
   C  20    3.2235     4.0855     2.5575     4.0009     3.7258     1.2917 
   C  21    3.2455     4.1479     4.0237     2.5799     1.3208     3.7380 
   C  22    3.0426     4.9562     4.0575     2.0787     0.8142     4.0319 
   C  23    4.9259     1.5612     4.8338     5.0326     4.0881     3.7573 
   C  24    4.3722     2.0793     4.3701     4.4383     3.4958     3.3740 
   F  25    5.9078     0.7693     5.9854     5.7821     4.6674     4.9773 
   F  26    7.0261     0.7722     7.0624     6.8910     5.7518     6.0044 
   F  27    7.0445     0.8074     6.8641     7.1243     6.1008     5.6949 
   F  28    5.9297     0.8045     5.7501     6.0582     5.0914     4.5992 
   C  29    5.5511     0.9002     5.5104     5.5646     4.5374     4.4420 
  Rh  30    2.0502     4.4017     2.3284     2.2916     1.8351     1.8872 
   C  31    2.9917     3.5243     3.2999     2.9344     2.0446     2.6592 
   C  32    2.9911     3.5022     2.9371     3.2955     2.6606     2.0410 
   C  33    2.1180     6.0360     0.8274     3.3928     3.8050     0.7405 
   C  34    2.1231     6.1069     3.4039     0.8317     0.7433     3.8163 
   H  35    3.7629     2.7259     3.6862     3.9691     3.1697     2.6849 
   H  36    5.4204     1.3842     5.1772     5.6394     4.7509     4.0075 

              C  13      C  14      C  15      C  16      C  17      C  18
              ------------------------------------------------------------------
   C  13    0.0000 
   C  14    1.9708     0.0000 
   C  15    2.5928     2.1477     0.0000 
   C  16    2.3042     1.5632     0.5903     0.0000 
   C  17    1.5017     2.4207     1.5692     1.6422     0.0000 
   C  18    2.0172     2.9146     1.6606     1.9090     0.5532     0.0000 
   C  19    1.3063     3.2430     3.7180     3.5308     2.2969     2.6378 
   C  20    0.7959     2.7398     2.9407     2.7919     1.5069     1.8765 
   C  21    2.7459     0.8064     2.2015     1.6366     2.9360     3.3621 
   C  22    3.2373     1.3045     3.0186     2.4536     3.6715     4.1283 
   C  23    2.5194     2.7901     0.9627     1.4149     1.0905     0.8713 
   C  24    2.0900     2.1954     0.6801     0.9148     0.8944     1.0146 
   F  25    3.7041     3.4647     1.3246     1.9016     2.3478     2.1004 
   F  26    4.7588     4.5749     2.4437     3.0141     3.3278     2.9707 
   F  27    4.5524     4.8350     2.7243     3.3106     3.0513     2.5689 
   F  28    3.4350     3.8016     1.7901     2.3433     1.9359     1.4784 
   C  29    3.2000     3.2698     1.1753     1.7528     1.7703     1.4678 
  Rh  30    1.0965     1.0466     2.5715     2.0836     2.1392     2.6914 
   C  31    1.4838     0.7534     1.6128     1.0955     1.6684     2.1626 
   C  32    0.7534     1.4838     1.8679     1.5511     1.1255     1.6777 
   C  33    2.0197     3.4551     4.6064     4.2706     3.4245     3.8620 
   C  34    3.4629     2.0290     4.1262     3.5362     4.3703     4.8947 
   H  35    1.3983     1.8815     1.2516     1.1612     0.5614     1.0342 
   H  36    2.8715     3.4472     1.6495     2.1187     1.3708     0.8813 

              C  19      C  20      C  21      C  22      C  23      C  24
              ------------------------------------------------------------------
   C  19    0.0000 
   C  20    0.7920     0.0000 
   C  21    4.0347     3.4917     0.0000 
   C  22    4.4625     4.0223     0.8176     0.0000 
   C  23    3.3849     2.5965     3.0351     3.8461     0.0000 
   C  24    3.1133     2.3246     2.4800     3.2823     0.5966     0.0000 
   F  25    4.6447     3.8542     3.4202     4.2200     1.2644     1.6172 
   F  26    5.5990     4.8206     4.4760     5.2565     2.2472     2.6983 
   F  27    5.1630     4.4313     4.9165     5.7298     2.1225     2.7001 
   F  28    4.1087     3.3546     3.9793     4.7967     1.0265     1.6200 
   C  29    4.0569     3.2719     3.3768     4.1939     0.6848     1.1792 
  Rh  30    2.2629     1.8907     1.8515     2.2001     2.8892     2.3251 
   C  31    2.7894     2.1727     1.3529     2.0200     2.0999     1.5044 
   C  32    2.0184     1.3524     2.1746     2.7881     1.9506     1.4399 
   C  33    1.3919     2.0073     4.2485     4.4314     4.4971     4.1053 
   C  34    4.4523     4.2426     2.0362     1.3775     4.8189     4.2244 
   H  35    2.4665     1.6908     2.3747     3.1152     1.1715     0.6918 
   H  36    3.5050     2.7542     3.7331     4.5410     0.7041     1.2633 

              F  25      F  26      F  27      F  28      C  29     Rh  30
              ------------------------------------------------------------------
   F  25    0.0000 
   F  26    1.1209     0.0000 
   F  27    1.5763     1.1083     0.0000 
   F  28    1.1083     1.5763     1.1209     0.0000 
   C  29    0.6474     1.5625     1.5654     0.6545     0.0000 
  Rh  30    3.8632     4.9793     5.0116     3.9049     3.5029     0.0000 
   C  31    2.9292     4.0501     4.1935     3.1245     2.6411     0.9914 
   C  32    3.0499     4.1382     4.0582     2.9405     2.6048     1.0138 
   C  33    5.7129     6.7443     6.4288     5.3368     5.1819     2.4188 
   C  34    5.4097     6.4909     6.8427     5.8272     5.2786     2.3818 
   H  35    2.3074     3.3764     3.2821     2.1670     1.8311     1.7452 
   H  36    1.4654     2.1533     1.6895     0.6042     0.8347     3.4259 

              C  31      C  32      C  33      C  34      H  35      H  36
              ------------------------------------------------------------------
   C  31    0.0000 
   C  32    0.8292     0.0000 
   C  33    3.2902     2.7420     0.0000 
   C  34    2.7512     3.2989     3.9916     0.0000 
   H  35    1.1287     0.7792     3.4144     3.8646     0.0000 
   H  36    2.7293     2.4328     4.7432     5.4735     1.6826     0.0000 




ATOMIC CHARGES
   C   1    0.0000000000
   C   2    0.0000000000
   C   3    0.0000000000
   C   4    0.0000000000
   P   5    0.0000000000
   P   6    0.0000000000
   O   7    0.0000000000
   B   8    0.0000000000
   O   9    0.0000000000
   O  10    0.0000000000
   C  11    0.0000000000
   C  12    0.0000000000
   C  13    0.0000000000
   C  14    0.0000000000
   C  15    0.0000000000
   C  16    0.0000000000
   C  17    0.0000000000
   C  18    0.0000000000
   C  19    0.0000000000
   C  20    0.0000000000
   C  21    0.0000000000
   C  22    0.0000000000
   C  23    0.0000000000
   C  24    0.0000000000
   F  25    0.0000000000
   F  26    0.0000000000
   F  27    0.0000000000
   F  28    0.0000000000
   C  29    0.0000000000
  Rh  30    0.0000000000
   C  31    0.0000000000
   C  32    0.0000000000
   C  33    0.0000000000
   C  34    0.0000000000
   H  35    0.0000000000
   H  36    0.0000000000


BOND ANGLES
   2    1    3   C2   C2   C2    107.408
   2    1    5   C2   C2    P    143.130
   3    1    5   C2   C2    P    109.462
   1    2    4   C2   C2   C2    107.401
   1    2    6   C2   C2    P    142.351
   4    2    6   C2   C2    P    110.248
   1    3    7   C2   C2   O3    107.655
   1    3   10   C2   C2   O2    126.913
   7    3   10   O3   C2   O2    125.432
   2    4    9   C2   C2   O2    127.114
   2    4    7   C2   C2   O3    107.138
   7    4    9   O3   C2   O2    125.748
   1    5   11   C2    P   C3    124.977
   1    5   14   C2    P   C3    126.870
  11    5   14   C3    P   C3    108.153
   2    6   12   C2    P   C3    124.853
   2    6   13   C2    P   C3    127.649
  12    6   13   C3    P   C3    107.497
   3    7    4   C2   O3   C2    110.398
  25    8   26    F   B3    F     93.296
  25    8   27    F   B3    F    177.619
  25    8   28    F   B3    F     89.504
  26    8   27    F   B3    F     89.085
  26    8   28    F   B3    F    177.200
  27    8   28    F   B3    F     88.114
   5   11   22    P   C3   C3    107.900
   5   11   34    P   C3   C3    127.807
  22   11   34   C3   C3   C3    124.294
   6   12   19    P   C3   C3    108.275
   6   12   33    P   C3   C3    126.539
  19   12   33   C3   C3   C3    125.186
   6   13   20    P   C3   C3    107.679
   6   13   32    P   C3   C3    130.742
  20   13   32   C3   C3   C3    121.579
   5   14   21    P   C3   C3    108.997
   5   14   31    P   C3   C3    130.742
  21   14   31   C3   C3   C3    120.261
  16   15   23   C2   C2   C3    129.741
  15   16   24   C2   C2   C3     47.991
  18   17   24   C2   C2   C3     85.554
  17   18   23   C2   C2   C3     97.391
  12   19   20   C3   C3   C3    105.852
  13   20   19   C3   C3   C3    110.697
  14   21   22   C3   C3   C3    106.882
  11   22   21   C3   C3   C3    108.069
  15   23   18   C2   C3   C2    129.700
  18   23   29   C2   C3   C3    140.923
  18   23   36   C2   C3   HC     67.055
  15   23   29   C2   C3   C3     89.377
  15   23   36   C2   C3   HC    163.245
  29   23   36   C3   C3   HC     73.868
  16   24   35   C2   C3   HC     91.498
  16   24   29   C2   C3   C3    113.059
  16   24   17   C2   C3   C2    130.376
  29   24   35   C3   C3   HC    155.443
  17   24   35   C2   C3   HC     38.878
  17   24   29   C2   C3   C3    116.565
  23   29   24   C3   C3   C3     21.413


TORSION ANGLES
   4    2    1    3      0.026
   4    2    1    5    179.974
   6    2    1    3    179.974
   6    2    1    5      0.026
   7    3    1    2      0.026
   7    3    1    5    179.974
  10    3    1    2    179.974
  10    3    1    5      0.026
   9    4    2    1    179.974
   9    4    2    6      0.026
   7    4    2    1      0.026
   7    4    2    6    179.974
  11    5    1    2    179.974
  11    5    1    3      0.026
  14    5    1    2      0.026
  14    5    1    3    179.974
  12    6    2    1    179.974
  12    6    2    4      0.026
  13    6    2    1      0.026
  13    6    2    4    179.974
   4    7    3    1      0.026
   4    7    3   10    179.974
  22   11    5    1    179.974
  22   11    5   14      0.026
  34   11    5    1      0.026
  34   11    5   14    179.974
  19   12    6    2    179.974
  19   12    6   13      0.026
  33   12    6    2      0.026
  33   12    6   13    179.974
  20   13    6    2    179.974
  20   13    6   12      0.026
  32   13    6    2      0.026
  32   13    6   12    179.974
  21   14    5    1    179.974
  21   14    5   11      0.026
  31   14    5    1      0.026
  31   14    5   11    179.974
  24   16   15   23      0.026
  24   17   18   23      0.026
  17   18   23   15      0.026
  17   18   23   29    179.974
  17   18   23   36    179.974
  20   19   12    6      0.026
  20   19   12   33    179.974
  19   20   13    6      0.026
  19   20   13   32    179.974
  22   21   14    5      0.026
  22   21   14   31    179.974
  21   22   11    5      0.026
  21   22   11   34    179.974
  18   23   15   16      0.026
  29   23   15   16    179.974
  36   23   15   16    179.974
  35   24   16   15    179.974
  29   24   16   15      0.026
  17   24   16   15    179.974
  24   29   23   18    179.974
  24   29   23   15      0.026
  24   29   23   36    179.974
   2    4    7    3      0.026
   9    4    7    3    179.974
  14   21   22   11      0.026
  12   19   20   13      0.026
  16   24   29   23    179.974
  35   24   29   23      0.026
  17   24   29   23      0.026
  16   24   17   18    179.974
  35   24   17   18    179.974
  29   24   17   18      0.026


CHIRAL ATOMS
  29   24   17   18      0.026
  29   24   17   18      0.026
  29   24   17   18      0.026
  29   24   17   18      0.026
  29   24   17   18      0.026
  29   24   17   18      0.026
  29   24   17   18      0.026
  29   24   17   18      0.026